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Industrial Gases

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الكلية كلية الهندسة     القسم هندسة الكيمياوية     المرحلة 4
أستاذ المادة علاء نور غانم الموسوي       6/13/2011 8:51:17 AM

Industrial gases perform varied and essential functions in the world. Some are raw materials for the manufacture of other chemicals. This is particularly true of CO2, O2, N2, H2, CH4 etc. This chapter will concentrate just on the production of H2&O2 gases.

Hydrogen and Oxygen Uses

 

Hydrogen has long been an important gaseous raw material for chemical and petroleum industries such as cyclohexanol, ammonia, stearin, isooctane, methanol.

 

Hydrogen is sold as gas and liquid. Liquid hydrogen is the most profitable, as it is

 

a friend of environment when used as a fuel in fuel cells.

 

A major use of oxygen is the production of steel in open hearth or basic oxygen furnaces. The steel industry also uses oxygen as well as the chemical industry which is the consumer of oxygen in such applications as acetylene, ethylene oxide, hydrocarbons and medical purposes.

 

4.2 Hydrogen Manufacture

 

Hydrogen is derived almost exclusively from carbonaceous primarily hydrocarbons or water. These materials are decomposed by the energy, which may be electrical, chemical, or thermal. Examples include electrolysis of water, steam reforming of hydrocarbons, and thermal dissociation of natural gas. Hydrogen is also produced by partial oxidation of hydrocarbons and by steam-hydrocarbon reforming process.

Hydrogen has long been an important gaseous raw material for chemical and petroleum industries such as cyclohexanol, ammonia, stearin, isooctane, methanol.Hydrogen is sold as gas and liquid. Liquid hydrogen is the most profitable, as it is a friend of environment when used as a fuel in fuel cells.

Water is capable of undergoing both oxidation at anode and reduction at cathode. Catalytically reacting a mixture of steam and hydrocarbons at an elevated temperature to form a mixture of H2 and oxides of carbon. Breakdown of water to H2 and O2 by electrolysis is usually carried out in dilute solution. For Partial Oxidation Processes  the starting material can use natural gas, refinery gas, or other hydrocarbon gas mixtures as feedstocks, but their chief advantage is that theses processes can also accept liquid hydrocarbon.

Coal as a source of hydrogen will assume increasing importance in the future as reserves of gaseous and liquid hydrocarbon feedstock decrease. Although coal was used in early water-gas and producer-gas plants for the manufacture of a H2-CO mixture, these plants cannot compete with more modern processes. A mixture of nitrogen, 1 volume, and hydrogen, 3 volumes, may be prepared from the cracking or dissociation of ammonia. This mixed gas can be used for hydrogenation because the nitrogen.

Water is capable of undergoing both oxidation at anode and reduction at cathode.

 

Breakdown of water to H2 and O2 by electrolysis is usually carried out in dilute solution. n is inert

 

 

 

 


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